Zinc sulfide is surely an inorganic compound with the chemical formula ZnS, one of the common sulfur-containing compounds. Due to its unique physical and chemical properties, zinc sulfide has numerous applications in many domains.
Attributes of zinc sulfide
Zinc sulfide is actually a white or slightly yellow powder usually present in nature in sphalerite. Its crystal structure is actually created by the alternating arrangement of sulfur ions and zinc ions, showing a hexagonal crystal structure. In dry air, zinc sulfide is stable rather than easily changed. However, when phosphorescent zinc sulfide is exposed to humid air or perhaps an environment containing moisture, it undergoes an oxidation reaction and gradually transforms into zinc sulfate.
How will be the crystal structure of zinc sulfide formed?
The crystal structure of zinc sulfide includes sulfur ions (S2-) and zinc ions (Zn2 ) arranged in accordance with a particular pattern. Inside the crystal structure, sulfur ions and zinc ions interact with one another through ionic bonds to form a stable crystal structure.
Specifically, the crystal structure of zinc sulfide could be considered a sphalerite-type structure formed by alternating arrangements of sulfur and zinc ions. Each zinc ion is in the middle of four sulfur ions inside the crystal structure, forming a coordination tetrahedral structure. Simultaneously, each sulfur ion is in the middle of four zinc ions, forming an identical coordination tetrahedral structure. In this structure, the interaction between sulfur and zinc ions is mainly through ionic bonding.
In addition, inside the crystal structure of zinc sulfide, the coordination tetrahedra of sulfur ions and zinc ions are interconnected in a certain way to form a three-dimensional crystal structure. This structure makes zinc sulfide highly stable and able to have a good crystal structure at high temperatures and under oxygenated conditions.
In summary, the crystal structure of zinc sulfide is actually a sphalerite-type structure formed by the interaction of sulfur ions and zinc ions through ionic bonding, which gives zinc sulfide a number of unique physical and chemical properties and thus has an array of applications in many fields.
Synthesis of zinc sulfide
Currently, there are various techniques for synthesizing zinc sulfide, as well as the following are among the frequently used synthesis methods:
Direct synthesis method: Mix the proper amount of sulfur powder and zinc oxide, heat to high temperature (about 500 ?), and you may get zinc sulfide. This method is simple and easy to make use of but requires raw materials of zinc oxide with high purity.
Reduction method: Zinc sulfide can be obtained by mixing a suitable amount of zinc oxide with a reducing agent (e.g., hydrogen, deadly carbon monoxide, etc.) and heating to your high temperature. This method requires the use of a reducing agent; the fee is higher, however it can get high-purity zinc sulfide products.
Precipitation method: Mix the proper amount of zinc sulfate solution with the appropriate amount of sodium sulfide solution, adjust the pH value to your certain range, and acquire white zinc sulfide precipitate. This method is not hard to operate and can be used for large-scale production.
High-temperature self-propagation method: High-purity zinc sulfide powder can be obtained by evenly mixing the proper amount of zinc oxide powder and high-purity sulfur powder and after that heating those to a higher temperature (about 600?) to trigger the self-propagation reaction. This method requires high-purity raw materials and special equipment, but high-quality zinc sulfide products can be obtained.
Applications of zinc sulfide
Due to its unique physical and chemical properties, zinc sulfide has numerous applications in many fields. The subsequent are among the main parts of application:
Zinc sulfide powder can be used inside the following applications:
Analytical reagent: Zinc sulfide powder can be used as an analytical reagent for determining the presence and content of certain substances, like for fluorescence analysis, colorimetric analysis, photometric analysis and so on.
Fluorescents: Zinc sulfide powder can manufacture various fluorescents, like fluorescent tubes, monitors, X-ray fluorescent screens and so on. Zinc sulfide powder is popular as a fluorescent material due to the high luminous efficiency and stability.
Light conductor: Zinc sulfide powder has good electrical conductivity and optical properties and can manufacture various light conductor materials, like solar cells, photodiodes, etc.
Paint and pigment: Zinc sulfide powder has high covering power and coloring power; it can be used as an additive for paint and pigment, utilized in the manufacture of all types of white paint, zinc white pigment, and so on.
Laser materials: Zinc sulfide powder could be used to manufacture various materials, like laser crystals and glass.
Optical instruments: Zinc sulfide powder can manufacture various optical instruments, like telescopes, microscopes, camera lenses, etc.
Catalyst: Zinc sulfide powder can catalyze certain chemical reactions, like alkylation and hydrogenation.
Rubber and plastic additives: Zinc sulfide powder can be used as an additive for rubber and plastic to enhance their properties like abrasion resistance, heat resistance and aging resistance.
Medical applications: Zinc sulfide powder can be utilized inside the medical field, like to prepare drugs, medical equipment, etc.
In summary, zinc sulfide powder, an important inorganic material, has numerous applications in many fields. Using the continuous progress of technology and science, its application areas will be further expanded.
How do the fluorescent properties of zinc sulfide work?
Absorption of light energy: When light strikes zinc sulfide, the zinc sulfide can absorb light energy and convert it into excitation energy for electrons. This excitation energy causes the electrons to jump from a lower to your higher energy level, which puts the zinc sulfide within an excited state.
Emission of fluorescence: When zinc sulfide inside the excited state returns for the low-energy state, it releases the stored energy by means of emitted photons. This released photon is fluorescence, as well as its wavelength is more than irradiated light. If trace quantities of activators, like Cu, Mn, Ag, etc., are put into zinc sulfide, it may emit fluorescence of different colors.
Fluorescence luminescence mechanism: The fluorescence luminescence mechanism is mainly made up of two processes, namely, excitation and radiation. Inside the excitation process, zinc sulfide absorbs light energy. It converts it to the excitation energy of electrons, making the electrons jump from the low for the high energy level. In radiation, the excited electrons go back to the low energy state, releasing photons, i.e., fluorescence.
In conclusion, the fluorescence property of zinc sulfide is made by its absorption of light energy as well as its conversion to the excitation energy of electrons, which in turn releases energy by means of emitted photons. This fluorescent property makes zinc sulfide have an array of applications in many fields, like fluorescent tubes, displays, and X-ray fluorescent screens.
As an important inorganic compound, zinc sulfide has numerous applications in many fields. By understanding its properties and synthetic methods, we could better use zinc sulfide’s advantages and characteristics and expand its applications in various fields. Meanwhile, the continuous exploration of brand new synthetic methods and application areas will assist you to promote greater progress inside the research and application of zinc sulfide.
High quality high purity zinc sulfide ZnS powder Supplier
Luoyang Tongrun Nano Technology Co. Ltd. (TRUNNANO) is actually a trusted world-wide chemical material zinc sulfide ZnS powder supplier & producer with more than 12-year-experience in providing tremendously high-quality chemicals and Nanomaterials, including boride powder, nitride powder, graphite powder, sulfide powder, 3D printing powder, etc.
If you are searching for top-quality zinc sulfide ZnSpowder, please feel free to contact us and send an inquiry.(email address: [email protected])
We accept payment via Credit Card, T/T, West Union, and Paypal. TRUNNANO will ship the goods to customers overseas through FedEx, DHL, by air, or by sea.
Recent Comments
No comments to show.